Just imagine if the Hulk went on another rampage and everybody gets their battle gear together--then you have Spidey, who decides to get a whole bunch of cookies to calm him down. Sweets make HIM feel better when HE'S upset, after all! Whether it would work or not is debatable, but the looks on everyone's faces at such an idea would be PRICELESS.
Listen. Peter interacting with the Hulk -
especially even the Hulk on a rampage - is my Favourite Thing. This kid is like a eighth of the Hulk’s size and about that in strength, but is that going to stop him from going out there when people are in danger? Hell no