surfactant

As fragile as a soap bubble seems, these films have remarkable powers of self-healing. The animation above shows a falling water droplet passing through a soap film without bursting it. An important factor here is that the water droplet is wet–passing a dry object through a soap film is a quick way to burst it, as those who have played with bubbles know. The droplet’s inertia deforms the soap film, creating a cavity. If the drop’s momentum were smaller, the film could actually bounce the droplet back like a trampoline, but here the droplet wins out. The film breaks enough to let the drop through, but its cavity quickly pinches off and the film heals thanks to the stabilizing effect of its soapy surfactants. (Image credit: H. Kim, source)

August 7, 1963: Trying to Save the President's Baby

Sometimes, it’s easy to forget how far we have come in the past fifty years. On August 7, 1963, First Lady Jackie Kennedy delivered her second son, Patrick Bouvier Kennedy. The baby was five and a half weeks premature and weighed 4 pounds 10 ½ ounces. Today, a baby born at 34 weeks enjoys a 98% survival rate. However, in 1963, if the premature baby developed respiratory distress, odds were that the baby would die. There simply was no treatment at that time. Sadly, in the early morning hours of August 9, 1963, as President Kennedy stood watch, Patrick Kennedy succumbed to “hyaline membrane disease”, despite being cared for by the most knowledgable medical team in the country.

Interestingly, when Patrick Kennedy died, most doctors didn’t even really understand what caused “hyaline membrane disease”. The common theory was that a glassy membrane formed making it nearly impossible for the baby’s lungs to extract sufficient oxygen when air was inhaled. However, after decades of research, doctors finally realized that 

(h)yaline membrane disease was not caused by the presence of something in the lungs but rather by the absence of something. The lungs of babies who died of hyaline membrane disease lacked a substance called surfactant, which lines the alveoli, the small air sacs at the end of the lungs’ numerous, branching airways. The problem did not lie only with breathing in, as had long been assumed, but also with breathing out. The baby took that first breath, perhaps even a good deep breath, as any baby would. But if the newborn baby’s immature lungs lacked surfactant, the alveoli tended to collapse when the baby breathed out. 

This understanding led to the eventual development of artificial surfactants, the practice of giving steroids (which speed up the natural production of surfactant) to women at risk of premature labor, and the introduction of better ventilator/respirator technology & methods. 

When people ask me if I want to return to a simpler time such as the 1950s or early 60s, I always think (for many reasons), “Are you crazy?" I have no desire to return to a time where infants born at 34 weeks had a 3% survival rate. Today that survival figure is 98%. Think about that. It’s a truly remarkable turnaround in a relatively short number of years. On what would have been his 49th birthday, I pause to pay respects to baby Patrick whose short life undoubtedly attracted public attention to hyaline membrane disease and helped fuel further research, leading to effective treatments that save the lives of tens of thousands of newborns each year. 

Clean-up of accidents like the 2010 Deepwater Horizon oil spill can be complicated by what goes on beneath the ocean surface. Variations in temperature and salinity in seawater create stratification, stacked layers of water with differing densities. When less dense layers are on top, the fluid is said to be stably stratified. Since oil is less dense than water, one might assume that buoyancy should make an oil plume should rise straight to the ocean surface. But the presence of additives or surfactants in the oil mixture plume can prevent that. With surfactants present, an oil mixture tends to emulsify, breaking into tiny droplets like a well-mixed salad dressing. Even if the density of the emulsion is smaller than the surrounding fluids, such a plume can get trapped at a density boundary, as seen in the photo above. Researchers report a critical escape height, which depending on the plume’s characteristics and stratification boundary, determines whether a plume escapes or becomes trapped.  (Image credit: R. Camassa et al.)

Science art: Driven. Evolving patterns over film on silicon wafer
Anton Darhuber, Benjamin Fischer and Sandra Troian
Microfluidic Research and Engineering Laboratory, Department of Chemical Engineering This image illustrates evolving dynamical patterns formed during the spreading of a surface-active substance (surfactant) over a thin liquid film on a silicon wafer. After spin-coating of glycerol, small droplets of oleic acid were deposited. The usually slow spreading process was highly accelerated by the surface tension imbalance that triggered a cascade of hydrodynamic instabilities. Such surface-tension driven flow phenomena are believed to be important for the self-cleaning mechanism of the lung as well as pulmonary drug delivery. source: Art of Science Competition
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Boiling water plays a major role in the steam cycles we use to generate power. One of the challenges in these systems is that it’s hard to control the rate of bubble formation when boiling. In this video, researchers demonstrate their new method for bubble control in a clever and amusing fashion. The twin keys to their success are surfactants and electricity. Surfactant molecules, like soap, have both a polar (hydrophilic) end and a non-polar (hydrophobic) end. By applying an electric field at the metal surface, the researchers can attract or repel surfactant molecules from the wall, making it either hydrophobic or hydrophilic depending on the field’s polarity. Since hydrophobic surfaces have a high rate of bubble formation, this lets the scientists essentially turn nucleation on and off with the flip of a switch! (Video credit: MIT Device Research Lab; see also: research paperMIT News Video, press release)

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LENOL 700

LENOL 700 is a non/ionic surfactant, multipurpose, with acidifying, penetrating and translocation action whose use increases the effectiveness of herbicides, insecticides, fungicides, foliar fertilizers and growth regulators.

LENOL 700 contains Lecithin and it is formulated as a unique technology to allow you to expect more from your pesticide application, as it delivers 5 important benefits.

* SPREADABILITY - provides better leaf spread to increase pesticide contact.
* ADHESION - Droplets remain on target to ensure pesticide effectiveness
* PENETRATION - Provides better breakdown of waxy leaf cuticle to allow for enhanced pesticide penetration into the plant.
* DROPLET MANAGEMENT - Better managing of the droplet size to minimize loss due to drift or evaporation.

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Another cool thing I’ve learned since starting medical school: lamellar bodies. Produced by Type II pneumocytes deep in the lung, they contain the protein and phospholipid components of surfactant. Surfactant decreases surface tension in the small alveoli to keep them from collapsing. 

Also, pretty bad ass that this picture was taken by shooting electrons through/around shit that’s so tiny. 

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Ferrofluids create all kinds of fascinating shapes when exposed to magnetic fields. In this video, Dianna from Physics Girl shows off what happens when you combine a ferrofluid with glowsticks and explains how ferrofluids get some of their unique properties. Ferrofluids consist of tiny nanoparticles of magnetic material that are surrounded by surfactants and suspended in a carrier fluid. This creates a fluid whose shape depends on gravity, surface tension, and the local magnetic field. By manipulating the relative strength of these forces, you can create everything from spikes to maze-like patterns to whatever this is. (Video credit and submission: Physics Girl)

Watch on fuckyeahfluiddynamics.tumblr.com

It is common in many industries to use oil as a defoamer to break up existing foams or prevent foams from forming. But with the right surfactants–additives that change the foam’s surface tension–it’s possible to make aqueous foams that are actually stabilized by the presence of oil. This video explores some of the ways that oil can interact with these kinds of foam, beginning with capillary action, which draws the oil up into the junctions between foam films. For more, see Piroird and Lorenceau. (Video credit and submission: K. Piroird)

Oil Dispersants

Oil spills are a very unfortunate reality of our world. Tankers filled with oil become damaged by rocks or become beached and eject their contents into the marine environment causing a lot of damage to local fauna and flora.

Due to the cohesive nature of oil it can be very hard to remove quickly. Microbial life and turbulence can break up the oil over time but because the oil stays together and gives the microbes a very small surface area to work with and movements in the ocean are not enough. it takes a very long time to break up the oil naturally. 

This is yet another job surfactants are employed into, oil dispersants which also contain solvents to dissolve the emulsifiers as many are solid at room temperature. The addition of surfactants breaks up the oil layer into smaller  droplets that have much larger surface area for microbes to begin decomposing the oil and ocean turbulence can also break the oil down much quicker.

There are some toxicity effects related to the dispersants however but they are used in a case by case circumstance depending on the dangers posed by the oil spill such as. Oil will have no effect to coral systems if they are subtidal. If a mangrove system is threatened they will be considered. This issue however is complicated if a coral system is close to a mangrove system because the oil droplets will be deposited into the water column which will have adverse effects on coral.

As such considerations are taking into account before they are used to protect a habitat currently effected by oil:

  • Expected sensitivity of exposed resource
  • Proportion of the resource that would be affected 
  • Recovery rates of the exposed resource

Oil dispersants are thus only used when the benefits of breaking down the oil outweigh the effects they will have on the environment. If they will benefit the majority of the habitat with possible damage to a couple of species they will be used because the habitat is conserved as a whole