sulfur

Crystallized sulfur

Known to be behind the characteristic odor of rotting eggs, sulfur is essential for all living cells. Cells make proteins that form strong chemical bonds called disulfide bridges between two adjacent sulfur atoms. These bridges give strength to our hair, outer skin, and nails. Eggs are loaded with sulfur because disulfide bridges are needed to form feathers, which explains why eggs smell on rotting. Because sulfur is easy to smell, natural gas lines–which are normally odorless–have sulfur additives to help people identify and smell a gas leak when it occurs.

Image by Dr. Edward Gafford.

2

Burning of Sulfur

Sulfur burns with a blue flame concomitant with formation of sulfur dioxide, notable for its peculiar suffocating odor. Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as benzene and toluene. 

The first and the second ionization energies of sulfur are 999.6 and 2252 kJ·mol−1, respectively. Despite such figures, the +2 oxidation state is rare, with +4 and +6 being more common. 

The fourth and sixth ionization energies are 4556 and 8495.8 kJ·mol−1, the magnitude of the figures caused by electron transfer between orbitals; these states are only stable with strong oxidants as fluorine, oxygen, and chlorine.

Reaction:   

  • S(s)  +  O2(g)  —>  SO2(g)
  • 2S(s)  +  3O2(g)  —>  2SO3(g)

Giffed by: rudescience  From: This video

In Your Element! The Chemistry of Fireworks

The art of using mixtures of chemicals to produce explosives is an ancient one to say the least. Black powder - a mixture of potassium nitrate, charcoal, and sulfur - was being used in China well before 1000 AD and is also used in military explosives, construction blasting and, of course, fireworks. Years and years ago fireworks just used to be basically rockets and loud bangs and the colours such as orange and yellow came from charcoal and iron fillings. However, great advances in chemistry in the 19th century had new compounds finding their way into fireworks. Salts of copper, strontium, and barium added some brilliant colours. Magnesium and aluminum metals gave a dazzling white light.

Keep reading