nitrogen monoxide


Pluto’s “icy heart” is a bright, two-lobed feature on its surface that has attracted researchers ever since its discovery by the NASA New Horizons team in 2015. Of particular interest is the heart’s western lobe, informally named Sputnik Planitia, a deep basin containing three kinds of ices – frozen nitrogen, methane and carbon monoxide – and appearing opposite Charon, Pluto’s tidally locked moon. Sputnik Planitia’s unique attributes have spurred a number of scenarios for its formation, all of which identify the feature as an impact basin, a depression created by a smaller body striking Pluto at extremely high speed.

A new study led by Douglas Hamilton, professor of astronomy at the University of Maryland, instead suggests that Sputnik Planitia formed early in Pluto’s history and that its attributes are inevitable consequences of evolutionary processes. The study was published in the journal Nature on December 1, 2016.

“The main difference between my model and others is that I suggest that the ice cap formed early, when Pluto was still spinning quickly, and that the basin formed later and not from an impact,” said Hamilton, who is lead author of the paper. “The ice cap provides a slight asymmetry that either locks toward or away from Charon when Pluto’s spin slows to match the orbital motion of the moon.”

Using a model he developed, Hamilton found that the initial location of Sputnik Planitia could be explained by Pluto’s unusual climate and its spin axis, which is tilted by 120 degrees. For comparison, Earth’s tilt is 23.5 degrees. Modeling the dwarf planet’s temperatures showed that when averaged over Pluto’s 248-year orbit, the 30 degrees north and south latitudes emerged as the coldest places on the dwarf planet, far colder than either pole. Ice would have naturally formed around these latitudes, including at the center of Sputnik Planitia, which is located at 25 degrees north latitude.

Hamilton’s model also showed that a small ice deposit naturally attracts more ices by reflecting away solar light and heat. Temperatures remain low, which attracts more ice and keeps the temperature low, and the cycle repeats. This positive feedback phenomenon, called the runaway albedo effect, would eventually lead to a single dominating ice cap, like the one observed on Pluto. However, Pluto’s basin is significantly larger than the volume of ice it contains today, suggesting that Pluto’s heart has been slowly losing mass over time, almost as if it was wasting away.

Even so, the single ice cap represents an enormous weight on Pluto’s surface, enough to shift the dwarf planet’s center of mass. Pluto’s rotation slowed gradually due to gravitational forces from Charon, just as Earth is slowly losing spin under similar forces from its moon. However, because Charon is so large and so close to Pluto, the process led to Pluto locking one face toward its moon in just a few million years. The large mass of Sputnik Planitia would have had a 50 percent chance of either facing Charon directly or turning as far away from the moon as possible.

“It is like a Vegas slot machine with just two states, and Sputnik Planitia ended up in the latter position, centered at 175 degrees longitude,” said Hamilton.

It would also be easy for the accumulated ice to create its own basin, simply by pushing down, according to Hamilton.

“Pluto’s big heart weighs heavily on the small planet, leading inevitably to depression,” said Hamilton, noting that the same phenomenon happens on Earth: the Greenland Ice Sheet created a basin and pushed down the crust that it rests upon.

While Hamilton’s model can explain both the latitude and longitude of Sputnik Planitia, as well as the fact that the ices exist in a basin, several other models were also presented in the December 1, 2016, issue of the journal Nature.

In one of those papers, UC Santa Cruz Professor of Earth and Planetary Sciences Francis Nimmo, Hamilton and their co-authors modeled how Sputnik Planitia may have formed if its basin was caused by an impact, such as the one that created Charon. Their results showed that the basin may have formed after Pluto slowed its rotation, migrating only slightly to its present location. If this late formation scenario proves correct, the properties of Sputnik Planitia may hint at the presence of a subsurface ocean on Pluto.

“Either model is viable under the right conditions,” said Hamilton. “While we cannot conclude definitively that there is an ocean under Pluto’s icy shell, we also cannot state that there is not one.”

Although Pluto was stripped of its status as a planet, an ice cap is a surprisingly Earth-like property. In fact, Pluto is only the third body – Earth and Mars being the others – known to possess an ice cap. The ices of Sputnik Planitia may therefore offer hints relevant to more familiar ices here on Earth.

anonymous asked:

33 w/ OiTen plz? Ta much :D


(Psst more college au)

33. “Something about you makes me want to commit extreme violence.” 

“Tooru. Toooru.” A voice sounded in his ear. “Tooooooru.” 

“What the hell do you want, Satori?!” He snapped. Tendou only smirked, straightening up and somehow looking down on him, despite them not even having an inch of height difference. “I’m trying to do my work.” 

“What do you think would happen if you combined nitrogen monoxide with carbon disulfide?” 

Tooru blinked, before scowling. “It would explode, we learned this last week. The ‘barking dog’ reaction, remember?” 

“Right, right.” He nodded. “What about hydrogen peroxide and potassium iodide?” 

“A prodigious amount of oxygen gas.” 

“What about-”

“Satori!” He snapped, turning towards him with a glare. “Y’know, something about you makes me want to extreme violence.” 

“I get that a lot.”

Thanks for the request, Anon! This was super fun to write ^^

Send me a (Tendou) ship + a number and I’ll write a short fic!  


Sunset on Pluto

NASA’s newly released images from New Horizons show a sunset refracting through Pluto’s atmosphere, evidence of some sort of exotic water cycle. Instead of water, however, the gases are largely of nitrogen, methane and carbon monoxide - every element of which is strongly represented in ice form on the Plutonian surface.

Somehow Pluto’s generating significant amounts of heat, enough to melt the material on its surface and erase impact craters. Much of this material evaporates into the atmosphere but how is still a mystery.

(Image credit: NASA/Johns Hopkins University Applied Physics Laboratory/Southwest Research Institute)

After the nitration, the reaction mixture was poured on 2 kg ice in a 5 liter Erlenmeyer flask and the product precipated as a white solid (at the bottom of the flask). 

During this, some nitric oxide evolved from this highly acidic solution what gave this foam as seen on the picture. The interesting is, that while nitric oxide (nitrogen monoxide) is separated from air (in the foam) it is a colorless gas, but when it is exposed to oxygen, it immediately turns brown, due it is oxidized to nitrogen dioxide: 2 NO + O2 —> 2 NO2