i’ve decided to make a masterpost that includes fic recommendations for each member seeing as i’ve gotten many requests for more suggestions. so voila my little cinnamon sticks, i hope this satisfies you!
Crystals of 2-iodobenzoic acid that crystallized out from the reaction mixture.
2-iodobenzoic acid is a quite easy to prepare chemical, made from anthranilic acid by the Sandmeyer reaction. It starts with the diazotization of anthranilic acid followed by a diazo replacement. First anthranilic acid is treated with nitrous acid in order to convert the amino group into the diazo group. The diazo group is ejected, yielding a carbocation which is then attacked by highly nucleophilic I− anion.
From o-iodobenzoic acid several chemicals could be made, on of these and probably one of the most famous is the IBX and the Dess-Martin Periodane.
Dess–Martin periodinane (DMP) is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. Compared to other reagents, it has several advantages that include milder conditions (room temperature, neutral pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the reagent in 1983.
It’s produced with a two step reaction, involving the oxidation of the iodine atom of the corresponding benzoic acid with Oxone or potassium-bromate and sulfuric acid, than treating the resulting IBX (2-iodoxybenzoic acid) with acetic anhydride. The only bad point in the synthesis, that the IBX and the DMP could explode if not treated properly.
Tonight’s skin care routine 🌒… I think I might be obsessed with The Ordinary. I’ve just been really impressed by their products. They suit my needs without extra frills. Cheap, effective, and simple. ✅
(each product below is under $20 🤑 )
Muji Sensitive Skin Cleansing Oil: I hate how thick and unspreadable this is. My skin seems to like it though, so I’ll use it up. 😕
Klairs Supple Preparation Facial Toner: ❤️
T.O. Caffeine Solution 5% + EGCG: TBH I haven’t noticed much of an effect on eye puffiness. Still, this is a hydrating eye serum that will last you FOREVER. A single drop is a generous amount for both eyes. Very cost effective.❓
T.O. Hyaluronic Acid 2% + B5: This is my first night using the serum, but I definitely notice an increase in facial plumpness. Sticky texture though.❓
T.O. Niacinamide 10% + Zinc 1% mixed with Cosrx Snail Essence (not pictured because I’m forgetful): ❤️
T.O. 100% Organic Cold-Pressed Rose Hip Seed Oil: ❤️
And on a side note; I’m almost done with my 30 day Neutrogena Light Mask Therapy! Its taken longer than a month because I tend to forget to use it, but I’m 3 uses away! I’ll try to buckle down so I can get my final thoughts out to you guys!
When your warden gf tries to impress you by killing a giant spider, but it turns out the giant spider she was trying to kill was actually Morrigan. Now her whole chestplate is covered in acidic spider spit.