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Scientists finally succeed in growing dolomite in the lab by dissolving structural defects during growth

For 200 years, scientists have failed to grow a common mineral in the laboratory under the conditions believed to have formed it naturally.

phys.org

For 200 years, scientists have failed to grow a common mineral in the laboratory under the conditions believed to have formed it naturally. Now, a team of researchers from the University of Michigan and Hokkaido University in Sapporo, Japan have finally succeeded, thanks to a new theory developed from atomic simulations. Their success resolves a long-standing geology mystery called the "Dolomite Problem." Dolomite—a key mineral in the Dolomite mountains in Italy, Niagara Falls, the White Cliffs of Dover and Utah's Hoodoos—is very abundant in rocks older than 100 million years, but nearly absent in younger formations. "If we understand how dolomite grows in nature, we might learn new strategies to promote the crystal growth of modern technological materials," said Wenhao Sun, the Dow Early Career Professor of Materials Science and Engineering at U-M and the corresponding author of the paper published today in Science. The secret to finally growing dolomite in the lab was removing defects in the mineral structure as it grows. When minerals form in water, atoms usually deposit neatly onto an edge of the growing crystal surface. However, the growth edge of dolomite consists of alternating rows of calcium and magnesium.