Dean & Castiel
How they met: How did a demon hunter and an angel get to be friends? Well, they work together now, but back when Dean was in Hell it was Castiel who pulled Dean out and brought him back to life. It doesn’t get much more epic than that.
Current relationship status: Still no actual romance between these two, but fans of the pairing still hold out hope for Destiel.
Love language: “Cas, I know you’re in there. I know you can hear me. Cas, it’s me. We’re family. We need you. I need you.” - Dean